How an emulsion holds
Oil and water naturally separate. An emulsion suspends tiny droplets of one inside the other and keeps them apart with an emulsifier — mustard, egg yolk, or honey — whose molecules grab both oil and water at once. Vigorous mixing breaks the oil into small enough droplets for the emulsifier to coat. No emulsifier, or droplets too big, and it separates.
A vinaigrette that stays together
The 3:1 oil-to-acid ratio is the starting point; adjust to taste.
- 1Start with acid and emulsifier. In a bowl or jar, combine the acid (vinegar or citrus) with a teaspoon of mustard, plus salt and pepper.
- 2Add oil slowly. Whisk constantly while drizzling the oil in a thin stream so it breaks into fine droplets the mustard can hold.
- 3Check the texture. It should look creamy and slightly thickened, not layered. Taste and balance with more acid or salt.
- 4Re-emulsify as needed. If it sits and separates, just whisk or shake it again before serving.
The same trick, scaled up
Mayonnaise is the same idea with egg yolk as the emulsifier and far more oil. Hollandaise (one of the five mother sauces) is a warm emulsion. And finishing a pan sauce with cold butter is a quick emulsion that gives it gloss. Once you see emulsification, you spot it everywhere.